Showing posts with label FRP. Show all posts
Showing posts with label FRP. Show all posts

Monday, February 26, 2018

RESIN TRANSFER MOULDING: (RTM) and its variation in FRP

RESIN TRANSFER MOULDING: (RTM):
It is an adaptation of Marco process.
Reinforcing material used is commonly continuous strand, glass fiber mat.
Process:
The reinforcing mat is clamped between the two halves of a male and female mould. The room temperature cured and catalyzed resin is injected through the injection ports, displacing the air through the other ports. Usually the resin is injected at the bottom and the air is ejected (exits) through the top ports which have transparent tubing inserts. So that when resin is seen in the tubing, injection can be stopped.
COLD PRESS MOULDING: (Variation in RTM)
Here the reinforcement is placed in the female half and the catalyzed resin is poured into the reinforcement. The mould is then closed so that the resin is distributed. The male and the female mould tightly fits in each other. Most uniform resin distribution is determined empirically and then consistency is accomplished easily.
Advantage (of both RTM and cold press moulding):
a.       Smooth surfaces on both sides of the part.
b.      Fast cycles.
c.       Lower part cost.
d.      Uniform wall thickness.
e.       Good dimensional control.
f.       Low cost plastic moulds can be used because high pressures are not involved.
g.      Process is particularly adaptable for moderate quantities of large parts.
Up to 100 lb or ft2 in area.

PULTRUSION process in FRP

Definition:
Automated method for producing continuous reinforced plastic shapes by pulling pre-impregnated reinforcing fibers through a heated die in which the resin is cured.
Impregnation:
Process carried out in an impregnator to thoroughly soak the material like wood, paper, or fabric with synthetic resin so that the resin gets within the body of the material. 
Process:
The roving strands are drawn through an impregnating tank and a squeeze bushing to remove the excess resin and air. The extrudate is then cured. There are two methods of producing Pultrusions based on method of curing the extrudate. They are:
1.         Tunnel oven process
2.         RF energy
Tunnel oven process:
a.       Here the wet roving bundles are made into rod stock.
b.      It is passed first through a shaping bushing to impart general desired circular shape.
c.       It is then circumferentially and spirally wound with cellophane tape.
d.      The Pultrusion then passes through the heated curing zones in the long oven for curing.
e.       The rod is then pulled by a pulling device and cut to length.
f.       Rectangular and other simple shapes can also be produced by this technique, especially if they are finished in a secondary operation.
g.      It is difficult to produce complex profiles or to retain dimensional tolerances or high finishes without secondary finishing because there is no shape restraint during cure.
RF energy:
a.       The wet roving bundle is subjected to RF cure when it is drawn into a shaping die.
b.      The final cure takes place within the short shaping tube because the cure obtained by this dielectric heating system is very fast.
c.       Any profile that can be extruded can be produced by this method.
d.      High surface finish is inherent and do not require secondary finishing.
Application:
It is new in the field of reinforced plastic structural shapes, but is developing rapidly. Items made are fishing rods, archery bows, hammer and axe handles, construction I and T beams, On-site tank construction.

CONTINUOUS LAMINATION in FRP

The process is identical to the flat sheet process with an addition of forming shoes in the oven stage to impart the desired corrugated configuration.
Reinforcing media like fiberglass mats, fabrics and papers can be used.
The resin impregnated system consists of an impregnating tank, doctor blade, roll coater or other type of resin metering device.
Process:
a.       The piles of reinforcement are drawn through a resin impregnating system.
b.      After impregnation a carrier sheet of cellophane or PE film is applied to each face of the web.
c.       The sandwich then passes through a set of squeeze rolls to remove excess resin and air. Here the final thickness is determined.
d.      The web is then passed through a long, tunnel oven with precisely controlled temperature zones. Here curing takes place. After curing the web emerges from the oven as a rigid sheet.
e.       The sheet is passed through the puller rolls and then it is trimmed by abrasive or diamond saws. The cellophane is stripped and the sheet is cut to length by a flying cut off saw.
f.       Sometimes the laminated decorative flat sheet is produced by a continuous method and sometimes by a translucent glazing panel and structural sheet for military and electronic application. However most of the product is used in corrugated sheet for the building industry.
Corrugated sheets are produced by hand laminating and press moulding techniques but most of the production is via continuous laminators.

INJECTION MOULDING in FRP

                     1.         Material:
                     2.         Polyester and Epoxy reinforced compounds with maximum reinforcement fiber length of approximately ½” are used.
                     3.         Process:
                     4.         It is similar to the Injection moulding of thermoplastic. However the barrel and screw or plunger is kept at relatively lower temperature and the material is injected into a mould kept at 150-1750C.
                     5.         Advantages:
a.       High production rates for very complex parts with almost complete automation.
Flash is minimal because parts are injected into a closed mould and thus post mould trimming is kept to a minimum.

Sunday, February 25, 2018

CONVENTIONAL EQUIPMENT USED FOR FRP

EQUIPMENT FOR GENERAL USE:
1.      Resin mixers
2.      Impregnation equipment
3.      Vacuum equipment
4.      Presses
5.      Miscellaneous equipment


1.         Resin mixers:
Resin mixing equipment runs the entire range from the bent rod in the hand drill motor to the continuous vacuum deaerated, proportional pump, in-line mixer.
The type of mixing equipment depend on the type of mixing manufacturing operation e.g. short runs of resin mix employs propeller type mixers. Some other typical mixers are lightening portable drum mixer, converted bakery dough breakers and other types of rotary and planetary paddle mixers.
For high production moulding and encapsulation, a metered, shot dispensing mixing equipment is used to
a.       Eliminate pot life problems
b.      Provide shot weight control
c.       Allow multi-station dispensing from a single system
d.      Improve house-keeping.
For continuous laminator or extruder, an in-line, proportional metering pump system is used to
a.       Get higher running speeds with hotter catalytic system
b.      Provide steady controllable flow
c.       Provide uniform mixture
For boat and other large area of hand lay up or spray up components, a pressure pot, spray mixing unit is used because of their compatibility with the rest of the processing equipment and the ability to deposit a relatively large volume of resin mix over extensive surfaces rapidly.
Regardless of the system used, they must be accompanied by the mix and/or the base resin if high quality end product is to be attained. 
2.         Impregnation equipment:
Different equipment used for impregnation have basically the same operating principle but they vary widely in the specific details. The four common preimpregnated form of reinforcement are fabrics, rovings, mats and chopped fibers.
Impregnation of sheet material (fabrics, woven roving and SMC material) produce usually a B-staged material or SMC. While the impregnation of BMC material (roving as continuous fibers or as chopped fibers) may or may not result in B-staged stock.
The impregnation equipment basically consist of
a.       Unwind stations for PE support films (top and bottom)
b.      An unwind station for reinforcement
c.       Impregnating area where the resin is applied
d.      A compacting area
e.       Oven curing tunnel or tower for B-staging
f.       Rewind station where the laminate is wound.
However for production of chopped fiber SMC, the sheet is formed at the machine and the impregnation is somewhat more complicated.
Application and control of resin:
It varies widely from station immersion and squeeze rolls to doctor blade techniques and many forms of roll coating. Complex control and read out system must be used in the B-staging area because proper temperature zoning and control is extremely critical to achieve quality and reproducibility. Many types of heating, depending on local economics, are used like gas, electricity, steam etc.
Impregnation of continuous fiber roving:
Here the fibers are simply run through a resin bath, then through squeeze rolls or a compaction die and then the fibers are directly applied to the part.
Preparation of premix BMC:
It consists of mechanically mixing chopped fibers, resin, catalysts, fillers, and other additives by various methods. One method employs a water jacketed chamber and spiral or sigma mixing blades and is used for batch preparation. Such a system contains automatic weighing and feed of the material. Continuous mixing and extruding equipment is also used. Where a rotating screw similar to the conventional extruder is used except that the L/D ration is less to minimize the glass fiber degradation. Automatic feed and metering mechanism assures a steady, proper flow of ingredients to the mixer. The product can be a putty like rope which then can be simply cut to length for moulding, thus eliminating the weighing operation.
Other continuous system for premix include:
a.       Chopping of the impregnated roving and then pelletizing, then running resin and reinforcement through meshing gears.
b.      Chopping the roving and impregnating the fibers on a belt.
3.         Vacuum equipment:
To choose the type of vacuum pump for a reinforced plastic plant, the specific operation must be determined e.g. In plants for vacuum bag lamination, small individual pumps are preffered than a central system because the pump can move with the job. While in a plant where primary de-aeration or vacuum impregnation is used, a central system with large receiver is desirable. In any case, precautions should be taken to insure adequate trap capacity between every job and the pump otherwise the system will not function for long time. Even with the best trap and filter system, some of the resin reach the pump in vapour form. The floating eccentric vane type of cylindrical pump can tolerate this type of service better.   
4.         Presses:
Specialized presses for the reinforced plastic differ from most other types of press in that they have relatively low ram forces compared to their platen area. However the premix moulders are looking for increased tonnage and faster closure speeds and the military job shops, moulding ablative components for rocketry use extremely high moulding pressures on outside components.
5.         Miscellaneous equipment:
Depending on the particular process being used, all or only part of the following equipment can be used:
a.       Various capacity scales for weighing the ingredients
b.      Several types of fiber cutters
c.       Spray equipment
d.      Polishers
e.       Rollers
Barcol hardness tester.

SMC Process as Raw stock preparation in FRP

SHEET MOULDING COMPOUND (SMC):
This class of material, made in sheet form upto ¼” thickness, consists basically 1-2” long, chopped strand glass fiber roving as the reinforcing material, a polyester resin and a number of additives. The principal additives here (besides the catalysts) are the thickeners, fillers, thermoplastic polymers and pigments.
The function of the thickener (MgO) is to cause a controlled increase in viscosity of the resin, after thorough fiber wetting has taken place. The thickening of the resin then insures a uniform flow of reinforcement and resin to allparts of the mould when heat and pressures are applied. This minimizes the problem of resin-rich or resin-starved areas found in B-staged material when heated and pressed.
The function of approximately 30% by weight of powdered thermoplastic resin is to decrease the shrinkage of the polyester resin. Such resin formulation are called low shrinkage or low-profile resin. SMC containing thermoplastic resins (acrylics, PVC, styrene copolymers, PE, etc.) can be compression moulded to extremely smooth, high gloss surfaces. Gel coats are not used, but the moulded parts are usually finished by painting with automotive primers and finished coats.
Process:
Here the SMC fibers are saturated with the resin by two doctor blades which meter the polymer on the PE films. The resin must be very accurately controlled to obtain uniform impregnation and because of the method of saturation, the fiber layer cannot be too thick up to ¼” approximately.

PREMIXES OR DMC OR BMC RAW STOCK PREPARATION METHOD FOR FRP

PREMIXES: (dough moulding compound DMC or bulk moulding compound BMC)
They are the mixtures of polyester resin; a mineral filler (usually CaCO3), clay, silica clay, etc.; reinforcing fibers (glass, nylon etc.); appropriate catalysts; pigments and lubricants.
Process:
The resin and filler are mixed to produce a thick pourable liquid or a soft putty like substance. To this material fibers are then carefully added and mixed. Improper or excessive mixing may cause breaking of glass fibers which may result in very rapid degradation of the physical properties of the moulding. The length of the glass fiber have a considerable effect on the final properties of the moulding compound. Shorter fiber result in low material strength and longer fiber do not disperse well in the mixing operation, are apt to break up and may interfere with flow in moulding operation.
Usually the premixed material is wrapped in PE film to minimize the loss of the styrene. The material can be stored for 3-4 weeks at room temperature depending on the catalyst used.
Often, the premix are extruded or rolled into long lengths or cords to obtain preforms of desired length, simply by chopping them.
Polyester premix or BMC are among the cheapest plastic moulding compounds. Epoxy resin based BMC have relatively higher cost.
Advantage:
The premixes can be moulded by compression or transfer moulding with fairly low pressure, fast cure cycles and high strengths.

WET LAYUP AND PREPEGS PROCESS IN FRP


WET LAY UP TECHNIQUE:
It is the simplest method, where continuous lengths of mats, fabrics or rovings are passed through a resin bath and through squeeze rolls. This process is used where material are required for immediate use or only in small or moderate quantities. The final product is usually quite tacky and somewhat difficult to handle especially when stored as rolls.
PREPEGS OR B-STAGED MATERIALS:
Here the fibers are drawn through a bath, squeeze rolls and then through one or more heating zones. In the heaters the laminate is stripped off solvents and other volatiles and then the resin is advanced to the B-stage so that relatively dry and only slightly tacky material results. The degree of B-staging achieved is a function of the temperature, speed of travel, resin content, and the resin type.
This process is used for laminates to be cured at high temperature or by UV radiation and usually result in material having relatively long shelf lives and can be easily handled and stored. The final product is known as a pre impregnated fabric or roving.

Saturday, March 18, 2017

RELEASE AGENTS for FRP



RELEASE AGENTS: (Parting agents or mold release)
Regardless of the type of reinforcement or the resin used, the parts have a tendency to stick to the mold surface. Hence some type of release agent is always used to facilitate removal of the part from the mold. The release agent functions by forming a barrier film between the mold surface and the part. Various materials used as release agents can be classified as:
1.      External release agents--applied to the mold surfaces.
2.      Internal release agents--combined with the resin.
·         EXTERNAL RELEASE AGENTS:
They can be further classified as--1) films, 2) film formers and 3) wipe-ONs.
FILMS:
It can be obtained in roll or sheet form. The film may be applied as a flat sheet cut to size or as thermoformed sheet made to conform to a 3-D contour e.g. Regenerated cellulose (Cellophane), PVA, Polyester, nylon, and Teflon films are usually used as flat sheets and PE, cellulose acetate, PVC and various fluorocarbon films can be easily thermoformed.
The film will satisfactorily prevent mold sticking and will usually stick to the part after curing so that it can be easily stripped off.
Selection Criteria:
Temperature at which the part is to be cured should be well below the softening temperature of the film material.
FILM FORMERS:
They can be applied either by brush or spry gun on the mold surface. Most common materials are: cellulose acetate lacquers, PVA and nylon solutions, heat cured fluorocarbon coatings and possibly varnishes and/or automobile type paint fillers which can be sanded to a high gloss finish.
These materials are generally used over porous surfaces like wood or plaster of paris. They are also used where the surface are to be filled and smoothed to remove scratches, pits, or the grain pattern of a wooden form. They are frequently used along with a wax, silicone, or fluorocarbon type wipe ON material.
WIPE-ONs:
They are applied with a wiping rag (for certain waxes), a brush (for oily material) or a spray, usually in the form of an aerosol can. In most cases after the initial application the mold is wiped with a rag to smoothen the mold surface. Most common materials are:
WAX: There are number of wax preparations ranging from pure carnauba wax to various soft paste waxes similar to automobile waxes. The pure carnauba wax is generally applied to hot molds.
Advantage:
1) High gloss can be obtained if the material is correctly applied and polished.
2) The mold can be used immediately with no drying or curing period required.
SILICONES:
Various Silicone materials are available in solution form and are wiped or brushed on. Some are air dried and others are heat cured. Silicones are also available in the form of aerosol solutions which are either air drying or heat curing.
FLUOROCARBONS:
The aerosol spray cans of fluorocarbon particles dispersed in a volatile solvent carrier have advantage like-- the excellent release properties and high temperature resistance. This allows them to be used with polymers which are curing at the highest temperature. However, the final gloss may not be as high as that obtained with paste wax.

In general, the use of wrong mold release can result in increased time for part removal or may result in damaged surface or parts due to mold sticking. A mold release should be chosen according to the post molding process being carried out.

·         INTERNAL RELEASE AGENTS:
The chemical compounds used as internal release agents are added to the resin by the manufacturer to minimize the mold sticking after cure. Metallic soaps like zinc or calcium stearate are used for polyester and phenolic resins. Silicone oils and high melting point waxes are used in epoxies. Organo-phosphates and waxes are used in polyester resin. The internal release agents work by being squeezed or exuded on the surface during cure of the resin.