Showing posts with label reinforced plastic. Show all posts
Showing posts with label reinforced plastic. Show all posts

Monday, February 26, 2018

RESIN TRANSFER MOULDING: (RTM) and its variation in FRP

RESIN TRANSFER MOULDING: (RTM):
It is an adaptation of Marco process.
Reinforcing material used is commonly continuous strand, glass fiber mat.
Process:
The reinforcing mat is clamped between the two halves of a male and female mould. The room temperature cured and catalyzed resin is injected through the injection ports, displacing the air through the other ports. Usually the resin is injected at the bottom and the air is ejected (exits) through the top ports which have transparent tubing inserts. So that when resin is seen in the tubing, injection can be stopped.
COLD PRESS MOULDING: (Variation in RTM)
Here the reinforcement is placed in the female half and the catalyzed resin is poured into the reinforcement. The mould is then closed so that the resin is distributed. The male and the female mould tightly fits in each other. Most uniform resin distribution is determined empirically and then consistency is accomplished easily.
Advantage (of both RTM and cold press moulding):
a.       Smooth surfaces on both sides of the part.
b.      Fast cycles.
c.       Lower part cost.
d.      Uniform wall thickness.
e.       Good dimensional control.
f.       Low cost plastic moulds can be used because high pressures are not involved.
g.      Process is particularly adaptable for moderate quantities of large parts.
Up to 100 lb or ft2 in area.

PULTRUSION process in FRP

Definition:
Automated method for producing continuous reinforced plastic shapes by pulling pre-impregnated reinforcing fibers through a heated die in which the resin is cured.
Impregnation:
Process carried out in an impregnator to thoroughly soak the material like wood, paper, or fabric with synthetic resin so that the resin gets within the body of the material. 
Process:
The roving strands are drawn through an impregnating tank and a squeeze bushing to remove the excess resin and air. The extrudate is then cured. There are two methods of producing Pultrusions based on method of curing the extrudate. They are:
1.         Tunnel oven process
2.         RF energy
Tunnel oven process:
a.       Here the wet roving bundles are made into rod stock.
b.      It is passed first through a shaping bushing to impart general desired circular shape.
c.       It is then circumferentially and spirally wound with cellophane tape.
d.      The Pultrusion then passes through the heated curing zones in the long oven for curing.
e.       The rod is then pulled by a pulling device and cut to length.
f.       Rectangular and other simple shapes can also be produced by this technique, especially if they are finished in a secondary operation.
g.      It is difficult to produce complex profiles or to retain dimensional tolerances or high finishes without secondary finishing because there is no shape restraint during cure.
RF energy:
a.       The wet roving bundle is subjected to RF cure when it is drawn into a shaping die.
b.      The final cure takes place within the short shaping tube because the cure obtained by this dielectric heating system is very fast.
c.       Any profile that can be extruded can be produced by this method.
d.      High surface finish is inherent and do not require secondary finishing.
Application:
It is new in the field of reinforced plastic structural shapes, but is developing rapidly. Items made are fishing rods, archery bows, hammer and axe handles, construction I and T beams, On-site tank construction.

CONTINUOUS LAMINATION in FRP

The process is identical to the flat sheet process with an addition of forming shoes in the oven stage to impart the desired corrugated configuration.
Reinforcing media like fiberglass mats, fabrics and papers can be used.
The resin impregnated system consists of an impregnating tank, doctor blade, roll coater or other type of resin metering device.
Process:
a.       The piles of reinforcement are drawn through a resin impregnating system.
b.      After impregnation a carrier sheet of cellophane or PE film is applied to each face of the web.
c.       The sandwich then passes through a set of squeeze rolls to remove excess resin and air. Here the final thickness is determined.
d.      The web is then passed through a long, tunnel oven with precisely controlled temperature zones. Here curing takes place. After curing the web emerges from the oven as a rigid sheet.
e.       The sheet is passed through the puller rolls and then it is trimmed by abrasive or diamond saws. The cellophane is stripped and the sheet is cut to length by a flying cut off saw.
f.       Sometimes the laminated decorative flat sheet is produced by a continuous method and sometimes by a translucent glazing panel and structural sheet for military and electronic application. However most of the product is used in corrugated sheet for the building industry.
Corrugated sheets are produced by hand laminating and press moulding techniques but most of the production is via continuous laminators.

INJECTION MOULDING in FRP

                     1.         Material:
                     2.         Polyester and Epoxy reinforced compounds with maximum reinforcement fiber length of approximately ½” are used.
                     3.         Process:
                     4.         It is similar to the Injection moulding of thermoplastic. However the barrel and screw or plunger is kept at relatively lower temperature and the material is injected into a mould kept at 150-1750C.
                     5.         Advantages:
a.       High production rates for very complex parts with almost complete automation.
Flash is minimal because parts are injected into a closed mould and thus post mould trimming is kept to a minimum.

PREMIX MOULDING (BMC MOULDING): (GUNK MOULDING) in FRP

In this process finished part is obtained while in BMC / DMC is the raw stock manufacturing process.
                     1.         It is a form of compression or transfer moulding.
                     2.         It uses dough or putty like moulding like compound called premix.
                     3.         Preparation of premix: The premix can be made by careful mixing of the ingredients in the mixer and in large production, this mixture is directly fed to an extruder which then prepares long lengths of material which is cut to sizes and fed to the press as premix.
                     4.         Compounding: It can be done at high pressure of several tons or at low pressure of several hundred pounds.
                     5.         Trouble shooting in processing premix compound:
Problem: Possibility of non-homogenous compound being prepared and/or a non-isotropic part being prepared.
Solution: Careful attention to mixing procedure and part design details (tending to accurate resin segregation or trap filler during compound flow in the mould)   
                     6.         Advantages: Rapid cycles at lower pressures with low cost materials.
                     7.         Applications:
a.       Mouldings are most competitive in areas where the die and sand castings were formerly used.
They find wide acceptance in electrical and electronics field, business machine housings, home appliances etc. because of good physical and electrical properties; ability to mould delicate inserts to precise tolerances.

SPRAY UP TECHNIQUE IN FRP

SPRAY UP TECHNIQUE:
Equipment: spray-up machine basically consists of:
1.      Roving cutter: May be mounted remotely (far away, not closely) or directly on the spray head.
2.      Two component resin catalyst delivery system: It has taken number of forms:
a.       Pressure pot system
b.      Air less system
c.       Double nozzle guns which mix catalyst and resin in the air
d.      Single mixing head guns.
3.      Glass delivery system: It also varies with the remote system:
a.       The chopped roving (A form of fibrous glass in which spun strands are woven into a tubular rope. The number of strands is variable but 60 is usual) is fed to the gun by hose instead of chopping at the point of delivery.
b.      Some guns do not chop at all but deliver the roving as a continuous strand which is laid in a swirl pattern.
Process:
a.       The unit (regardless of configuration) combines a catalyzed resin with an accelerated resin.
b.      The glass fibers are wetted with this mixture which is sprayed on the mould surface.
c.       Some spray guns are used to spray gel coats and some used to spray the resin, catalyst and a powered filler simultaneously.
Advantages:
Any large reinforced plastic structures can be build up simply and very rapidly.
Disadvantages:
The sprayed composite must be rolled by hand to remove the air and obtain sufficient density. Hence labour costs are equivalent to the hand lay-up techniques used to produce structures with good physical properties. The process will not yield consistently high properties.
Applications:
The process was initially used to make studio sets. Now it is greatly accepted in the areas where physical properties are not of primary importance like large outdoor display signs, tank linings, shower and tub enclosures, roofing etc. Gel coating and spray-up are very compatible and their combination produces moulding with very fine single surface finishes.

Sunday, February 25, 2018

MATERIAL PREPARATION TECHNIQUES USED IN FRP

1.         PREFORMING:
Definition: (in RP industry)
A technique used to arrange chopped glass fiber in the exact shape of a part to be moulded by the matched die moulding methods.
Process:
The chopped fiber (1.5” long usually) are deposited uniformly over the screen surface having the shape of the final moulded part. Then a small amount of binder resin is applied. Deposition proceeds until sufficient preform thickness is obtained to provide the optimum glass: resin ratio in the moulded part. Then the preform is heated, on the screen, until the binder resin cures, so that the preform is sufficiently sound and can be stripped from the screen and transported to the press for final moulding.
SMC preforms:
The preform is also applied to the use of fully impregnated SMC material which is precut or cut and stapled to fit a mould prior press curing.
Non SMC prefroms:
There are two methods for producing the non SMC preforms:
a.       Directed fiber preforming (or open preforming)
b.      Plenum chamber preforming

1.      Directed fiber preforming (or open preforming):
 Here the cut fibers are sprayed manually on a rotating screen through which air is being drawn to create a pressure drop at the screen interface. This suction holds the fiber in place on the screen while the operator directs the airborne screen of fiber to all areas of the screen. The operator also intermittently sprays the proper amount of an aqueous emulsion having 5% concentration of polyester or acrylic liquid binder. When the fiber build up is complete, the preform is oven cured and removed from the screen. The percentage of binder varies between 2-10% of the finished weight.
Machine:
Several type of machines are available depending on the size and desired production rate. On average size preforms, a common type is a four station rotary mount for the screens where:
1st screen is being sprayed
2nd screen is in the oven curing position
3rd screen is being stripped  
4th screen in in the ready position
Extremely large preform machine have only one screen.
After preforming, a hood lowers over the screen to form an oven, and the air is redirected through a heat exchanger to provide curing temperature.
Advantages:
Preforms with varying wall thickness, buildup areas can be produced because a wide range of machine sizes are available.
Disadvantages:
The uniformity of product depends almost entirely on the operator’s skill.
2.      Plenum chamber preforming:
It is similar to the directed fiber method and only differs in the method of applying the fiber to the screen. It is an adaptation of the old felt-hat forming machine.
Here the rotating screen is positioned in a plenum chamber and air is drawn through the screen. The roving cutter is mounted at the top of the plenum and the cut fiber falls on a rotating spinner which distributes the fiber uniformly in the plenum chamber. The fibers then “snow” down into the screen. The liquid resin binder is usually applied by spray gun, but in some machines, powder binder is sifted on from a vibrator feeder.
Advantage:
The product is uniform after the initial set up. The process can be completely automated, thus reducing the labour cost.
Disadvantage:
Restriction to uniform wall thickness, difficulty of initial set up on some types of parts and the compounding of the fiber distribution problem as size increases.
2.         FABRIC AND MATERIAL TAILORING:
When only small number of parts are required, tailored sections can be cut from impregnated raw stock by the use of hand shears or knives. For production of large numbers of parts inexpensive steel rule dies can be used or the material may be piled up in number of layers and cut, from a pattern, using a special textile cutting machine. If very simple shapes are required e.g. discs, then commercially available dies may be procured at normal costs from machine shop.

CONVENTIONAL EQUIPMENT USED FOR FRP

EQUIPMENT FOR GENERAL USE:
1.      Resin mixers
2.      Impregnation equipment
3.      Vacuum equipment
4.      Presses
5.      Miscellaneous equipment


1.         Resin mixers:
Resin mixing equipment runs the entire range from the bent rod in the hand drill motor to the continuous vacuum deaerated, proportional pump, in-line mixer.
The type of mixing equipment depend on the type of mixing manufacturing operation e.g. short runs of resin mix employs propeller type mixers. Some other typical mixers are lightening portable drum mixer, converted bakery dough breakers and other types of rotary and planetary paddle mixers.
For high production moulding and encapsulation, a metered, shot dispensing mixing equipment is used to
a.       Eliminate pot life problems
b.      Provide shot weight control
c.       Allow multi-station dispensing from a single system
d.      Improve house-keeping.
For continuous laminator or extruder, an in-line, proportional metering pump system is used to
a.       Get higher running speeds with hotter catalytic system
b.      Provide steady controllable flow
c.       Provide uniform mixture
For boat and other large area of hand lay up or spray up components, a pressure pot, spray mixing unit is used because of their compatibility with the rest of the processing equipment and the ability to deposit a relatively large volume of resin mix over extensive surfaces rapidly.
Regardless of the system used, they must be accompanied by the mix and/or the base resin if high quality end product is to be attained. 
2.         Impregnation equipment:
Different equipment used for impregnation have basically the same operating principle but they vary widely in the specific details. The four common preimpregnated form of reinforcement are fabrics, rovings, mats and chopped fibers.
Impregnation of sheet material (fabrics, woven roving and SMC material) produce usually a B-staged material or SMC. While the impregnation of BMC material (roving as continuous fibers or as chopped fibers) may or may not result in B-staged stock.
The impregnation equipment basically consist of
a.       Unwind stations for PE support films (top and bottom)
b.      An unwind station for reinforcement
c.       Impregnating area where the resin is applied
d.      A compacting area
e.       Oven curing tunnel or tower for B-staging
f.       Rewind station where the laminate is wound.
However for production of chopped fiber SMC, the sheet is formed at the machine and the impregnation is somewhat more complicated.
Application and control of resin:
It varies widely from station immersion and squeeze rolls to doctor blade techniques and many forms of roll coating. Complex control and read out system must be used in the B-staging area because proper temperature zoning and control is extremely critical to achieve quality and reproducibility. Many types of heating, depending on local economics, are used like gas, electricity, steam etc.
Impregnation of continuous fiber roving:
Here the fibers are simply run through a resin bath, then through squeeze rolls or a compaction die and then the fibers are directly applied to the part.
Preparation of premix BMC:
It consists of mechanically mixing chopped fibers, resin, catalysts, fillers, and other additives by various methods. One method employs a water jacketed chamber and spiral or sigma mixing blades and is used for batch preparation. Such a system contains automatic weighing and feed of the material. Continuous mixing and extruding equipment is also used. Where a rotating screw similar to the conventional extruder is used except that the L/D ration is less to minimize the glass fiber degradation. Automatic feed and metering mechanism assures a steady, proper flow of ingredients to the mixer. The product can be a putty like rope which then can be simply cut to length for moulding, thus eliminating the weighing operation.
Other continuous system for premix include:
a.       Chopping of the impregnated roving and then pelletizing, then running resin and reinforcement through meshing gears.
b.      Chopping the roving and impregnating the fibers on a belt.
3.         Vacuum equipment:
To choose the type of vacuum pump for a reinforced plastic plant, the specific operation must be determined e.g. In plants for vacuum bag lamination, small individual pumps are preffered than a central system because the pump can move with the job. While in a plant where primary de-aeration or vacuum impregnation is used, a central system with large receiver is desirable. In any case, precautions should be taken to insure adequate trap capacity between every job and the pump otherwise the system will not function for long time. Even with the best trap and filter system, some of the resin reach the pump in vapour form. The floating eccentric vane type of cylindrical pump can tolerate this type of service better.   
4.         Presses:
Specialized presses for the reinforced plastic differ from most other types of press in that they have relatively low ram forces compared to their platen area. However the premix moulders are looking for increased tonnage and faster closure speeds and the military job shops, moulding ablative components for rocketry use extremely high moulding pressures on outside components.
5.         Miscellaneous equipment:
Depending on the particular process being used, all or only part of the following equipment can be used:
a.       Various capacity scales for weighing the ingredients
b.      Several types of fiber cutters
c.       Spray equipment
d.      Polishers
e.       Rollers
Barcol hardness tester.

TMC method as raw stock preparation For FRP

THICK MOULDING COMPOUNDS (TMC):
It is a recent method of preparing SMC. The material is made in sheets similar to SMC, with thickness upto 2”. It also have many characteristic of BMC but have improved physical properties and can be continually processed.
Process:
In TMC machine the impregnation takes place in the nip of the two rapidly counter rotating rolls, whose spacing can be varied to provide controlled, thorough fiber saturation. Though TMC is apparently superior, SMC & BMC are the most widely used materials.

SMC Process as Raw stock preparation in FRP

SHEET MOULDING COMPOUND (SMC):
This class of material, made in sheet form upto ¼” thickness, consists basically 1-2” long, chopped strand glass fiber roving as the reinforcing material, a polyester resin and a number of additives. The principal additives here (besides the catalysts) are the thickeners, fillers, thermoplastic polymers and pigments.
The function of the thickener (MgO) is to cause a controlled increase in viscosity of the resin, after thorough fiber wetting has taken place. The thickening of the resin then insures a uniform flow of reinforcement and resin to allparts of the mould when heat and pressures are applied. This minimizes the problem of resin-rich or resin-starved areas found in B-staged material when heated and pressed.
The function of approximately 30% by weight of powdered thermoplastic resin is to decrease the shrinkage of the polyester resin. Such resin formulation are called low shrinkage or low-profile resin. SMC containing thermoplastic resins (acrylics, PVC, styrene copolymers, PE, etc.) can be compression moulded to extremely smooth, high gloss surfaces. Gel coats are not used, but the moulded parts are usually finished by painting with automotive primers and finished coats.
Process:
Here the SMC fibers are saturated with the resin by two doctor blades which meter the polymer on the PE films. The resin must be very accurately controlled to obtain uniform impregnation and because of the method of saturation, the fiber layer cannot be too thick up to ¼” approximately.