Sunday, February 25, 2018

CONVENTIONAL EQUIPMENT USED FOR FRP

EQUIPMENT FOR GENERAL USE:
1.      Resin mixers
2.      Impregnation equipment
3.      Vacuum equipment
4.      Presses
5.      Miscellaneous equipment


1.         Resin mixers:
Resin mixing equipment runs the entire range from the bent rod in the hand drill motor to the continuous vacuum deaerated, proportional pump, in-line mixer.
The type of mixing equipment depend on the type of mixing manufacturing operation e.g. short runs of resin mix employs propeller type mixers. Some other typical mixers are lightening portable drum mixer, converted bakery dough breakers and other types of rotary and planetary paddle mixers.
For high production moulding and encapsulation, a metered, shot dispensing mixing equipment is used to
a.       Eliminate pot life problems
b.      Provide shot weight control
c.       Allow multi-station dispensing from a single system
d.      Improve house-keeping.
For continuous laminator or extruder, an in-line, proportional metering pump system is used to
a.       Get higher running speeds with hotter catalytic system
b.      Provide steady controllable flow
c.       Provide uniform mixture
For boat and other large area of hand lay up or spray up components, a pressure pot, spray mixing unit is used because of their compatibility with the rest of the processing equipment and the ability to deposit a relatively large volume of resin mix over extensive surfaces rapidly.
Regardless of the system used, they must be accompanied by the mix and/or the base resin if high quality end product is to be attained. 
2.         Impregnation equipment:
Different equipment used for impregnation have basically the same operating principle but they vary widely in the specific details. The four common preimpregnated form of reinforcement are fabrics, rovings, mats and chopped fibers.
Impregnation of sheet material (fabrics, woven roving and SMC material) produce usually a B-staged material or SMC. While the impregnation of BMC material (roving as continuous fibers or as chopped fibers) may or may not result in B-staged stock.
The impregnation equipment basically consist of
a.       Unwind stations for PE support films (top and bottom)
b.      An unwind station for reinforcement
c.       Impregnating area where the resin is applied
d.      A compacting area
e.       Oven curing tunnel or tower for B-staging
f.       Rewind station where the laminate is wound.
However for production of chopped fiber SMC, the sheet is formed at the machine and the impregnation is somewhat more complicated.
Application and control of resin:
It varies widely from station immersion and squeeze rolls to doctor blade techniques and many forms of roll coating. Complex control and read out system must be used in the B-staging area because proper temperature zoning and control is extremely critical to achieve quality and reproducibility. Many types of heating, depending on local economics, are used like gas, electricity, steam etc.
Impregnation of continuous fiber roving:
Here the fibers are simply run through a resin bath, then through squeeze rolls or a compaction die and then the fibers are directly applied to the part.
Preparation of premix BMC:
It consists of mechanically mixing chopped fibers, resin, catalysts, fillers, and other additives by various methods. One method employs a water jacketed chamber and spiral or sigma mixing blades and is used for batch preparation. Such a system contains automatic weighing and feed of the material. Continuous mixing and extruding equipment is also used. Where a rotating screw similar to the conventional extruder is used except that the L/D ration is less to minimize the glass fiber degradation. Automatic feed and metering mechanism assures a steady, proper flow of ingredients to the mixer. The product can be a putty like rope which then can be simply cut to length for moulding, thus eliminating the weighing operation.
Other continuous system for premix include:
a.       Chopping of the impregnated roving and then pelletizing, then running resin and reinforcement through meshing gears.
b.      Chopping the roving and impregnating the fibers on a belt.
3.         Vacuum equipment:
To choose the type of vacuum pump for a reinforced plastic plant, the specific operation must be determined e.g. In plants for vacuum bag lamination, small individual pumps are preffered than a central system because the pump can move with the job. While in a plant where primary de-aeration or vacuum impregnation is used, a central system with large receiver is desirable. In any case, precautions should be taken to insure adequate trap capacity between every job and the pump otherwise the system will not function for long time. Even with the best trap and filter system, some of the resin reach the pump in vapour form. The floating eccentric vane type of cylindrical pump can tolerate this type of service better.   
4.         Presses:
Specialized presses for the reinforced plastic differ from most other types of press in that they have relatively low ram forces compared to their platen area. However the premix moulders are looking for increased tonnage and faster closure speeds and the military job shops, moulding ablative components for rocketry use extremely high moulding pressures on outside components.
5.         Miscellaneous equipment:
Depending on the particular process being used, all or only part of the following equipment can be used:
a.       Various capacity scales for weighing the ingredients
b.      Several types of fiber cutters
c.       Spray equipment
d.      Polishers
e.       Rollers
Barcol hardness tester.

TMC method as raw stock preparation For FRP

THICK MOULDING COMPOUNDS (TMC):
It is a recent method of preparing SMC. The material is made in sheets similar to SMC, with thickness upto 2”. It also have many characteristic of BMC but have improved physical properties and can be continually processed.
Process:
In TMC machine the impregnation takes place in the nip of the two rapidly counter rotating rolls, whose spacing can be varied to provide controlled, thorough fiber saturation. Though TMC is apparently superior, SMC & BMC are the most widely used materials.

SMC Process as Raw stock preparation in FRP

SHEET MOULDING COMPOUND (SMC):
This class of material, made in sheet form upto ¼” thickness, consists basically 1-2” long, chopped strand glass fiber roving as the reinforcing material, a polyester resin and a number of additives. The principal additives here (besides the catalysts) are the thickeners, fillers, thermoplastic polymers and pigments.
The function of the thickener (MgO) is to cause a controlled increase in viscosity of the resin, after thorough fiber wetting has taken place. The thickening of the resin then insures a uniform flow of reinforcement and resin to allparts of the mould when heat and pressures are applied. This minimizes the problem of resin-rich or resin-starved areas found in B-staged material when heated and pressed.
The function of approximately 30% by weight of powdered thermoplastic resin is to decrease the shrinkage of the polyester resin. Such resin formulation are called low shrinkage or low-profile resin. SMC containing thermoplastic resins (acrylics, PVC, styrene copolymers, PE, etc.) can be compression moulded to extremely smooth, high gloss surfaces. Gel coats are not used, but the moulded parts are usually finished by painting with automotive primers and finished coats.
Process:
Here the SMC fibers are saturated with the resin by two doctor blades which meter the polymer on the PE films. The resin must be very accurately controlled to obtain uniform impregnation and because of the method of saturation, the fiber layer cannot be too thick up to ¼” approximately.

PREMIXES OR DMC OR BMC RAW STOCK PREPARATION METHOD FOR FRP

PREMIXES: (dough moulding compound DMC or bulk moulding compound BMC)
They are the mixtures of polyester resin; a mineral filler (usually CaCO3), clay, silica clay, etc.; reinforcing fibers (glass, nylon etc.); appropriate catalysts; pigments and lubricants.
Process:
The resin and filler are mixed to produce a thick pourable liquid or a soft putty like substance. To this material fibers are then carefully added and mixed. Improper or excessive mixing may cause breaking of glass fibers which may result in very rapid degradation of the physical properties of the moulding. The length of the glass fiber have a considerable effect on the final properties of the moulding compound. Shorter fiber result in low material strength and longer fiber do not disperse well in the mixing operation, are apt to break up and may interfere with flow in moulding operation.
Usually the premixed material is wrapped in PE film to minimize the loss of the styrene. The material can be stored for 3-4 weeks at room temperature depending on the catalyst used.
Often, the premix are extruded or rolled into long lengths or cords to obtain preforms of desired length, simply by chopping them.
Polyester premix or BMC are among the cheapest plastic moulding compounds. Epoxy resin based BMC have relatively higher cost.
Advantage:
The premixes can be moulded by compression or transfer moulding with fairly low pressure, fast cure cycles and high strengths.

WET LAYUP AND PREPEGS PROCESS IN FRP


WET LAY UP TECHNIQUE:
It is the simplest method, where continuous lengths of mats, fabrics or rovings are passed through a resin bath and through squeeze rolls. This process is used where material are required for immediate use or only in small or moderate quantities. The final product is usually quite tacky and somewhat difficult to handle especially when stored as rolls.
PREPEGS OR B-STAGED MATERIALS:
Here the fibers are drawn through a bath, squeeze rolls and then through one or more heating zones. In the heaters the laminate is stripped off solvents and other volatiles and then the resin is advanced to the B-stage so that relatively dry and only slightly tacky material results. The degree of B-staging achieved is a function of the temperature, speed of travel, resin content, and the resin type.
This process is used for laminates to be cured at high temperature or by UV radiation and usually result in material having relatively long shelf lives and can be easily handled and stored. The final product is known as a pre impregnated fabric or roving.

LIST MATERIAL (RAW STOCK) PREPARATION TECHNIQUES IN FRP


MATERIAL PREPARATION TECHNIQUES (RAW STOCK):
Reinforced plastic consists of two essential components viz.:
The fibrous material and the liquid resin.
The fibers must be thoroughly coated with resin so that all the air in the fiber texture is replaced with resin. Various methods are employed to produce this raw stock which then can be made to conform a particular mould contour.
LIST OF TECHNIQUES:
1.      Wet layup technique
2.      Prepegs or B-staged materials
3.      Premixes
4.      Sheet moulding compound (SMC)
5.      Thick moulding compound (TMC)

MATERIAL HANDLING IN FRP

STORAGE AND HANDLING OF MATERIAL used for FRP:
RESIN:
1.      All the resins used in reinforced plastics should be stored in a cool, dry place.
2.      Epoxy resins are not as sensitive to the effects of storage temperature as are polyesters and phenolics and hence do not require storage below room temperature.
3.      Resins which are catalyzed and/or advanced to the B-stage may require a refrigerated storage.
4.      Resins in storage should be kept in tightly sealed containers to prevent the evaporation of volatile monomers and solvents especially for polyesters, phenolics and low viscosity grades of epoxies.
5.      Material, especially polyesters should be stored in containers that exclude light. Common containers are steel drums, tin cans or brown light-proof bottles.
6.      Various monomers and solvents, associated with resins must also be stored under conditions similar to the resin with which they are used and adequate ventilation should be provided to prevent the accumulation of fumes which can otherwise become a fire hazard. Also adequate grounding (earthing) should be provided on all equipment to dissipate any static charges.
7.      When the material which is stored under refrigeration, is used, the container should not be opened until the resin has reached the room temperature to avoid moisture condensation on the resin.
CATALYSTS, HARDENING AGENTS AND ACCELERATORS:
1.      They must be stored in a manner similar to their corresponding resin.
2.      Catalysts for polyesters should be treated with additional precaution. As powerful oxidizing material, they should be stored such that fire can be prevented.
REINFORCEMENTS:
1.      There are no toxic or fire hazards in the storage or handling of glass fibre reinforcements. However organic reinforcement may cause smoke or fume which result in a fire.
2.      In general the reinforcement material must be stored in a dry atmosphere to minimize moisture pickup and to insure high quality mouldings.
CATALYSED RESINS AND B-STAGED FABRICS:
1.      Refrigerated storage is necessary for all catalyzed resins and B-staged fabrics. The lower the temperature, the longer will be the usable life.
2.      The catalyzed resin should be kept in sealed container and B-staged fabrics should be wrapped in several layers of cellophane or Polyethylene (PE) film when in storage.
3.      The material should be allowed to reach the room temperature before being opened or unwrapped to avoid possible moisture condensation on the catalyzed material.
ANCILLARY MATERIALS:
Ancillary materials such as parting agents, sealants, films, fillers, and pigments must be stored under normal room temperature storage conditions.